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Cyclopropylboronic Acid 环丙硼酸

规格: 95%
CAS: 411235-57-9
产品编号: H94203
MDL: MFCD04038750
品牌: INFI
Chemical Namecyclopropylboronic acid
CAS Number411235-57-9
Alfabeta NameCYCLOPROPYLBORONICACID
MDL NumberMFCD04038750
MDL NumberMFCD04038750
Synonym CYCLOPROPYLBORONIC ACID Cyclopropaneboronic acid
PubChem Substance ID24881728
Chemical Name TranslationCyclopropylboronic acid环丙硼酸
LabNetwork Molecule IDLN00009534
GHS Symbol
Warnings IRRITANT, IRRITANT-HARMFUL
WGK Germany3
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P308+P313
    Signal word Danger
    Hazard statements
    • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
    • H318 Causes serious eye damage 严重伤害眼睛
    • H302 Harmful if swallowed 吞食有害
      Hazard Codes T Xn
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S37 Wear suitable gloves 戴适当手套;
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • {SA}
        • 1. Tambe, Y. B.; et al. , Microwave-assisted N-cyclopropylation of pyridinols with cyclopropyl boronic acid Synth. Commun. 9th ed., 42 , 1341-1348, (2012)
        • {SA}
        • 2. Haneda, S.; Sudo, K.; Hayashi, M. , Ni- and Cu-catalyzed coupling reactions using 2-(4,5-dihydro-1H-imidazo-2-yl)phenol as a versatile phosphine-free ligand Heterocycles 1st ed., 84 , 569-575, (2012)
        • {SA}
        • 3. Zhang, M.; et al. , Facile synthesis of aryl(het)cyclopropane catalyzed by palladacycle Tetrahedron 3rd ed., 68 , 900-905, (2012)
        • {SA}
        • 4. Rousseaux, S.; Liegault, B.; Fagnou, K. , Palladium(0)-catalyzed cyclopropane C-H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives Chem. Sci. 1st ed., 3 , 244-248, (2012)
        • {SA}
        • 5. Lu, W.; et al. , Palladium-Catalyzed Decarboxylative Coupling of Isatoic Anhydrides with Arylboronic Acids Org. Lett. 22th ed., 13 , 6114-6117, (2011) 摘要
        • {SA}
        • {SA} 6. Kubota, A.; Sanford, M. S., Palladium-catalyzed ligand-directed oxidative functionalization of cyclopropanes Synthesis 16 , 2579-2589, (2011)
        • {SA}
        • 7. Li, W.; et al. , A Mild Palladium-Catalyzed Suzuki Coupling Reaction of Quinoline Carboxylates with Boronic Acids Adv. Synth. Catal. 10th ed., 353 , 1671-1675, (2011)
        • {SA}
        • 8. Zheng, H.; et al. , Copper-catalyzed arylation of arylboronic acids with aldehydes Synlett 11 , 1626-1630, (2011)
        • {SA}
        • 9. Dai, C.; et al. , 2-(2-Aminothiazol-4-yl)pyrrolidine-based tartrate diamides as potent, selective and orally bioavailable TACE inhibitors Bioorg. Med. Chem. Lett. 10th ed., 21 , 3172-3176, (2011) 摘要
        • {SA}
        • {SA} Tetrahedron Lett. 43 , 6987-6990, (2002)
        • {SA}
        • J. Am. Chem. Soc. 128 , 12634, (2006) 摘要
        • {SA}
        • {SA} Benard S.; Neuville, L.; Zhu, J. J. Org. Chem. 73 , 6441, (2008) 摘要
        • 411235-57-9 H94203 Cyclopropylboronic Acid
环丙硼酸

          化学属性

          Mol. FormulaC3H7BO2
          Mol. Weight85.90
          Melting Point90-95
          TSCANo