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(Bromomethyl)cyclopropane (溴甲基)环丙烷

规格: 98%
CAS: 7051-34-5
产品编号: H91330
MDL: MFCD00001306
品牌: INFI
Chemical NameCyclopropylmethyl Bromide
CAS Number7051-34-5
Alfabeta NameCYCLOPROPYLMETHYLBROMIDE
MDL NumberMFCD00001306
Synonym Cyclopropylmethyl bromide {LY} Cyclopropylmethyl bromide {} {LY} Cyclopropylmethyl bromide {} {} {LY} Cyclopropylmethyl bromide {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropy
EC Number230-331-8
Beilstein Registry Number605296
PubChem Substance ID81503
Chemical Name Translation溴甲基环丙烷
InChIKeyAEILLAXRDHDKDY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008111
InChIInChI=1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2
Canonical SMILESBrCC1CC1
GHS Symbol
Warnings IRRITANT, KEEP COLD, FLAMMABLE
Signal word Warning
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
    Risk Statements
    • R10 Flammable 易燃
    • R22 Harmful if swallowed 吞咽有害
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P242 Use only non-sparking tools. 只能使用无火花工具。
      • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P264+P265
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P312
      • P301+P317
      • P302+P352
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
      • P319
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P330 Rinse mouth. 漱口
      • P332+P313
      • P332+P317
      • P337+P313
      • P337+P317
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P362+P364
      • P370+P378
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Packing GroupIII
        UN Number 1993
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H302 Harmful if swallowed 吞食有害
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes 3 Xn
          Hazard Class3
          Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
        • 用于有机合成中构建环丙烷甲基基团（cyclopropylmethyl- group）
        • {uni_hamburg} Short: II/25C
        • {uni_hamburg} Short: EINECS
        • {ALF} O-Alkylation of phenols (KO-t-Bu/DMF) has been used as a means of protection. The cyclopropylmethyl ethers are stable to reducing agents (metal hydride, H2, Birch), but selectively cleaved by aqueous methanolic HCl: Chem. Pharm. Bull., 23, 2878 (1975).
        • {ALD} Beilstein: 5,IV,14
        • {uni_hamburg} Short: II/14a
          • 7051-34-5 H91330 (Bromomethyl)cyclopropane (溴甲基)环丙烷

          化学属性

          Mol. FormulaC4H7Br
          Mol. Weight135.00
          Boiling Point105-107°C at 760 mmHg
          Density1.392
          Refractive indexn20/D 1.457(lit.)
          Flash Point41°C
          TSCANo
          Appearance 无色透明、易燃液体，无异味。密度1.433g/ml，沸点102-108℃，折射率1.4385。溶解于乙醇，醚，丙酮，苯。
          Danger-Level乙类
          Melting Point87-90 °C

          *以上化合物性质及应用等信息仅供参考

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