Chemilly-天津启瑞生物科技有限公司

Bromocyclopropane 溴代环丙烷

规格: 98.5%

CAS: 4333-56-6

产品编号: H72331

MDL: MFCD00001271

品牌: INFI

Chemical Name	Bromocyclopropane
CAS Number	4333-56-6
Alfabeta Name	CYCLOPROPYLBROMIDE
MDL Number	MFCD00001271
EC Number	224-375-7
Beilstein Registry Number	1900287
Synonym	Bromocyclopropane {LY} Bromocyclopropane {} {LY} Bromocyclopropane {} {} {LY} Bromocyclopropane {} {} {} {LY} Bromocyclopropane {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY}
PubChem Substance ID	78037
Chemical Name Translation	溴代环丙烷
Reaxys-RN	1900287
InChIKey	LKXYJYDRLBPHRS-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00008749
InChI	InChI=1S/C3H5Br/c4-3-1-2-3/h3H,1-2H2
Canonical SMILES	BrC1CC1

GHS Symbol

Warnings	LACHRYMATOR, FLAMMABLE
Signal word	Danger
WGK Germany	3
Safety Statements
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S29 Do not empty into drains 不要排入下水道； S33 Take precautionary measures against static discharges 对静电采取预防措施； S36 Wear suitable protective clothing 穿戴适当的防护服； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S37 Wear suitable gloves 戴适当手套； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
R11 Highly flammable 非常易燃 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P233 Keep container tightly closed. ?保持容器密闭。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。 P241+P242+P243 P242 Use only non-sparking tools. 只能使用无火花工具。 P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P264+P265 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P302+P352 P302+P352+P332+P313+P362+P364 P303+P361+P353 P304+P340 P305+P351+P338 P305+P351+P338+P337+P313 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P319 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P332+P313 P332+P317 P337+P313 P337+P317 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P362+P364 P370+P378 P403+P233 P403+P235 P405 Store locked up. 上锁保管。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing Group	II
UN Number	1993 UN 1993 3/PG 2
Hazard statements
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	3 F,Xi
Storage condition	-20°C {LY} -20°C 2-8°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Class	3

本品是重要的药物合成中间体，可用于合成环丙沙星、恩罗沙星和斯帕沙星等多种含环丙基的药物及氟喹诺酮类抗菌药物。

{ALD} Beilstein: 5,IV,6

{ALF} The Grignard reagent functions as an allyl anion equivalent in the reaction with thioacetals catalyzed by Dichlorobis(triphenylphosphine)nickel(II), 13930: J. Am. Chem. Soc., 111, 9119 (1989):

{ALF} The lithio-derivative reacts with Bis(cyclopentadienyl)titanium dichloride, A11456, to give bis(cyclopropyl)titanocene, which reacts with carbonyl compounds to give alkylidenecyclopropane derivatives: Tetrahedron Lett., 34, 943 (1993). Similarly, esters and lactones give enol ethers and acetylenes give vinylcyclopropanes.

4333-56-6 H72331 Bromocyclopropane
溴代环丙烷

化学属性

Mol. Formula	C3H5Br
Mol. Weight	120.98
Boiling Point	69°C at 760 mmHg
TSCA	T
Density	1.51
Refractive index	1.4570 to 1.4610
Flash Point	-6.67°C
Appearance	浅黄色至无色透明液体，沸点67-69℃，折光率(nD20) 1.4605，密度(d420) 1.5120，闪点-6℃。
Solubility	immiscible

*以上化合物性质及应用等信息仅供参考

手性催化剂及配体

合成砌块

医药中间体

Bromocyclopropane 溴代环丙烷

规格: 98.5%

化学属性

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