## Allyltrimethylsilane 烯丙基三甲基硅烷

##### 规格: 97%
CAS: 762-72-1

MDL: MFCD00008635

1 .如乙烯基三甲基硅烷作为一个“乙”合成子，用于3+2环加成反应，应用于有机合成过程中

2.如烯丙基三甲基硅烷，作为一个烯丙基化试剂，应用于艾日布林或者前列素类似物的合成中。

TiCl3（OiPr）

3.作为聚合引发剂，或者烯姪共聚物，参与烯姪聚合，形成功能性有机硅材料，如耐水性硅胶 粘合剂，修饰聚氟乙烯等

 技术优势产品纯度高，具有百公斤生产能力

Chemical Name Allyltrimethylsilane 3-(TRIMETHYLSILYL)PROPENE 3-(Trimethylsilyl)-1-propene 3-(Trimethylsilyl)propene 3-(三甲基甲硅烷基)丙烯 3-TRIMETHYLSILYL-1-PROPENE ALLYLTRIMETHYLSILANE Allyltrimethylisilane Allyltrimethylsilane {PubChem} allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {PubChem} allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { MFCD00008635 762-72-1 212-104-5 906755 69808 906755 烯丙基三甲基硅烷 LN00008514 InChI=1S/C6H14Si/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3 C[Si](C)(C)CC=C
GHS Symbol
Signal word Danger 3 S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；S33 Take precautionary measures against static discharges 对静电采取预防措施；S36 Wear suitable protective clothing 穿戴适当的防护服；S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；S37 Wear suitable gloves 戴适当手套；S9 Keep container in a well-ventilated place 保持容器在通风良好的场所； R11 Highly flammable 非常易燃R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。P233 Keep container tightly closed. ?保持容器密闭。P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。P242 Use only non-sparking tools. 只能使用无火花工具。P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。P264+P265 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。P302+P352 P302+P352+P312+P362+P364 P303+P361+P353 P304+P340 P305+P351+P338 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。P319 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。P332+P313 P332+P317 P337+P313 P337+P317 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用P362+P364 P370+P378 P403+P233 P403+P235 P405 Store locked up. 上锁保管。P501 Dispose of contents/container to..… 处理内容物/容器..... II 1993 UN 1993 3/PG 2 H225 Highly flammable liquid and vapour 高度易燃液体和蒸气H315 Causes skin irritation 会刺激皮肤H319 Causes serious eye irritation 严重刺激眼睛H335 May cause respiratory irritation 可能导致呼吸道刺激 Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter 3 F;Xi 3 0-6°C 2-8°C, stored under nitrogen
• 用于高分子有机硅化合物的合成
• {ALF} Has also been used, in the presence of a catalyst such as p-TsOH, I2, Br2 or TfOH, as a silylating agent for alcohols, phenols and carboxylic acids: Tetrahedron Lett., 21, 835 (1980); J. Org. Chem., 46, 5212 (1981). The advantage over more conventional silylation methods is that the only by-product is the neutral gas propene.
• {ALF} Reactions with electrophiles illustrate the &#223;-effect (see Appendix 4); e.g. acid chlorides with a Lewis acid give allyl ketones: J. Organomet. Chem., 85, 149 (1975):
• {uni_hamburg} Short: III/35C4
• {ALF} More recent studies have shown that TMS cyclopentanes are also formed in these reactions via a competing [3+2] cycloaddition mechanism: Tetrahedron, 49, 9955 (1993). Chemoselective addition to aldehydes can be accomplished in the presence of a ketone, using Scandium(III)&#x00AD; trifluoromethanesulfonate hydrate, 40566 as catalyst: Synthesis, 1822 (1998).
• {ALF} In the presence of F-, functions as an allyl anion equivalent, affording homoallylic alcohols from carbonyl compounds: Tetrahedron Lett., 3043 (1978), and adding to a variety of Michael acceptors: Tetrahedron Lett., 25, 3213 (1984); J. Org. Chem., 51, 1745 (1986). For a review of reactivity in the presence of Lewis acids and F-, see: J. Prakt. Chem./ Chem. Ztg., 336, 375 (1994).
• {ALF} Similarly, carbonyl compounds are converted to homoallylic alcohols: J. Organomet. Chem., 69, C15 (1974). In the TiCl4 promoted reaction with enones, behaves as an allyl anion equivalent, giving the product of conjugate addition (Hosomi-Sakurai reaction): J. Am. Chem. Soc., 99, 1673 (1977); 105, 2354 (1983); Org. Synth. Coll., 7, 443 (1990):
• {ALD} Merck: 14,10335
• {uni_hamburg} Short: III/35F
• {ALD} Merck: 14,10335
• Beilstein:4(3)1854
• #### 化学属性

Mol. Formula C6H14Si 114.26 0.719 1.4060 to 1.4080 7°C(lit.) Yes 84-88 不溶 无色液体。沸点44℃（2.4kPa），相对密度1.1628（20/4℃），折光率1.4675（20℃）。能与有机溶剂混合，不溶于水。