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Hexamethyldisilathiane 六甲基二硅硫烷

规格: 98%, SpcSeal
CAS: 3385-94-2
产品编号: H57844
MDL: MFCD00014851
品牌: INFI

有机硅烷类化合物主要应用在有机合成及有机硅材料领域。在有机合成中,硅烷作为羟基 保护基大量存在,如三甲基氯硅烷,TBSCI,有时作为一个合成子载体存在,如乙烯基三甲基 硅烷,烯丙基三甲基硅烷,六甲基二硅硫烷等,从而实现相应的官能团化反应。有机硅材料领域有硅烷偶联剂、硅油(硅脂、硅乳液、硅表面活性剂)、高温硫化硅橡胶、液体硅橡胶、硅 树脂、封端剂,含硅复合共聚物等。

应用介绍及参考文献

1 .如乙烯基三甲基硅烷作为一个“乙”合成子,用于3+2环加成反应,应用于有机合成过程中

  

参考文献:Vinyltrimethylsilane, Glenn J. Fegley Gerald L. Larson, Encyclopedia of Reagents for Organic Synthesis, 2008.


2.如烯丙基三甲基硅烷,作为一个烯丙基化试剂,应用于艾日布林或者前列素类似物的合成中。

TiCl3(OiPr)

参考文献:W020050118565, WO2019102490


参考文献:Gary A. Sulikowski et al Org. Lett. 2019, 21, 10048-10051


参考文献:Gary A. Sulikowski et al Org. Lett. 2019, 21, 10048-10051

3.作为聚合引发剂,或者烯姪共聚物,参与烯姪聚合,形成功能性有机硅材料,如耐水性硅胶 粘合剂,修饰聚氟乙烯等

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Chemical NameHexamethyldisilathiane
Synonym Bis(trimethylsilyl)sulfur; Hexamethyldisilathiane; Hexamethyldisilthian; Hexamethyldisilthiane; Hexamethyldisilyl sulfide; Hexamethyldisilylthiane HEXAMETHYLDISILATHIANE Hexamethyldisilthian { Hexamethyldisilylsulfide Bis(trimethylsilyl)sulfide, GC 95% Bis(trimethylsilylsulfide)Hexamethyldisilthiane 1,1,1,3,3,3-Hexamethyldisilathian 1,1,1,3,3,3-Hexamethyldisilathiane 六甲基二硅硫烷,98% NSC 252160 双(三甲基硫化硅) Hexamethylpropanedisilathiane Hexamethyldisilylthiane 硫甲基二硅 双(三甲基硅烷基)硫化物 Disilathiane, hexamethyl- Bis(trimethylsilyl)sulfur BIS(TRIMETHYLSILYL) SULFIDE 95+% 1,1,1,3,3,3-Hexamethyl-disilathiane Bis(trimethylsilyl) sulfide
MDL NumberMFCD00014851
CAS Number3385-94-2
EC Number222-201-4
Beilstein Registry Number4(4)4033
PubChem Substance ID76920
Reaxys-RN1698358
Chemical Name Translation六甲基二硅硫烷
InChIKeyRLECCBFNWDXKPK-UHFFFAOYSA-N
LabNetwork Molecule IDLN01742638
InChIInChI=1S/C6H18SSi2/c1-8(2,3)7-9(4,5)6/h1-6H3
MDL NumberMFCD00014851
CAS Number3385-94-2
GHS Symbol
Packing GroupII
UN Number 1993
Risk Statements
    Safety Statements
      WGK Germany3
      Hazard statements
      • H301+H311+H331
      • H226 Flammable liquid and vapour 易燃液体和蒸气
      • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
      • H331 Toxic if inhaled 吸入中毒
      • H301 Toxic if swallowed 吞食有毒
      • H311 Toxic in contact with skin 皮肤接触中毒
        Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
        Precautionary statements
        • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
        • P304+P340+P312
        • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
        • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
        • P303+P361+P353
        • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
        • P302+P352+P312+P362+P364
        • P501 Dispose of contents/container to..… 处理内容物/容器.....
        • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
        • P370+P378
        • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P301+P312+P330
        • P301+P310
        • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
        • P233 Keep container tightly closed. ?保持容器密闭。
        • P241+P242+P243
        • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
        • P403+P235
          Signal word
          Storage condition Flammables area Air Sensitive
          Hazard Codes T
          Hazard Class3
        • {uni_hamburg} Short: II/25D
        • Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms
        • Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
        • Editor: Kuchitsu, K.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/25D
        • Year: 2003
        • Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
        • ISBN: 3-540-42860-7
        • ISBN: 978-3-540-42860-2
        • Internet Resource: DOI:10.1007/b75952
        • RefComment: VIII, 569 pages. Hardcover
        • RefComment: Written for scientists and researchers in the fields of chemistry and physics
        • Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
        • {uni_hamburg} Short: III/35C4
        • Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
        • Author: Gupta, R.R.; Platzer, N.
        • Editor: Gupta, R.R.; Lechner, M.D.
        • Source: Landolt-Börnstein, New Series
        • Volume: III/35C4
        • Year: 2001
        • Keyword: Hydrogen 1; Nuclear Magnetic Resonance
        • ISBN: 3-540-41059-7
        • ISBN: 978-3-540-41059-1
        • Internet Resource: DOI:10.1007/b76570
        • RefComment: VII, 299 pages. With CD-ROM. Hardcover
        • Abstract: This volume provides a comprehensive
        • 3385-94-2 H57844 Hexamethyldisilathiane
六甲基二硅硫烷

          化学属性

          Mol. FormulaC6H18SSi2
          Mol. Weight178.44
          Density0.846
          Refractive index1.4590 to 1.4620
          Flash Point23°C(lit.)
          TSCAYes
          Boiling Point163°C(lit.)
          Mol. FormulaC6H18SSi2
          Mol. Weight178.44
          Density0.846
          Appearance colorless liq.
          Stabilitystore cold
          Boiling Point164°C