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2-Adamantanone 2-金刚烷酮

规格: 98%

CAS: 700-58-3

产品编号: H42068

MDL: MFCD00074737

品牌: INFI

Chemical Name	2-adamantanone
CAS Number	700-58-3
Alfabeta Name	ADAMANTANONE 2-
MDL Number	MFCD00074737
PubChem Substance ID	64151
Beilstein Registry Number	1210235
EC Number	211-847-2
Reaxys-RN	1210235
Synonym	Adamantanone {LY} Adamantanone {} {LY} Adamantanone {} {} {LY} Adamantanone {} {} {} {LY} Adamantanone {} {} {} {} {LY} Adamantanone {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adamantanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation	金刚烷酮
Wiswesser Line Notation	L66 B6/B-H/DI A B- C 1B I AVTJ
LabNetwork Molecule ID	LN00175135
InChI	InChI=1S/C10H14O/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2
Canonical SMILES	O=C1[C@H]2C[C@@H]3C[C@@H](C[C@H]1C3)C2

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 780 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCJOAU Pharmaceutical Chemistry Journal (English Translation).  Translation
   of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013)  No.1-
   1967-  Volume(issue)/page/year: 10,454,1976

Warnings	IRRITANT
WGK Germany	2
RTECS	AU5018000
Personal Protective Equipment	Eyeshields, Gloves
Signal word	Warning
Safety Statements
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触； S22 Do not breathe dust 不要吸入粉尘； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements

Precautionary statements
P273 Avoid release to the environment. 避免释放到环境中。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H402 Harmfultoaquaticlife 对水生生物有害。
Hazard Codes	Xi
Storage condition	2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

It was used in the synthesis of dispiro N-Boc-protected 1,2,4-trioxane and (+/-)-1-(adamantan-2-yl)-2-propanamine.

{ALF} Preparation of highly-substituted alkenes by the Wittig reaction gives poor yields with adamantanone. The route involving addition of a Grignard or alkyllithium reagent is to be preferred: J. Org. Chem., 54, 1375 (1989).

{uni_hamburg} Short: III/35E

{ALF} Reductive coupling (TiCl3/Li) gives (adamantylidene)adamantane, an example of a general method for the synthesis of highly-substituted alkenes: Org. Synth. Coll., 7, 1 (1990).

{uni_hamburg} Short: II/14a

化学属性

Mol. Formula	C10H14O
Mol. Weight	150.22
Melting Point	256-258°C
Density	1.105
TSCA	No
Solubility	methanol: 0.1 g/mL, clear
Boiling Point	211.78 °C at 760 mmHg

*以上化合物性质及应用等信息仅供参考

手性催化剂及配体

合成砌块

医药中间体

2-Adamantanone 2-金刚烷酮

规格: 98%

化学属性

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