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1-(Trimethylsilyl)propyne 1-(三甲基硅基)丙炔

规格: 98%

CAS: 6224-91-5

产品编号: H38919

MDL: MFCD00009271

品牌: INFI

Chemical Name	Trimethyl(prop-1-yn-1-yl)silane
CAS Number	6224-91-5
Synonym	Trimethyl(prop-1-yn-1-yl)silane {LY} Trimethyl(prop-1-yn-1-yl)silane {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	87576914
EC Number	228-314-5
Beilstein Registry Number	1071311
MDL Number	MFCD00009271
Reaxys-RN	1071311
Chemical Name Translation	1-(三甲基硅基)丙炔
InChIKey	DCGLONGLPGISNX-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00194943
Canonical SMILES	CC#C[Si](C)(C)C

GHS Symbol

WGK Germany	3
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H335 May cause respiratory irritation 可能导致呼吸道刺激 H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	3 F;Xi
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P233 Keep container tightly closed. ?保持容器密闭。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。 P241+P242+P243 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P302+P352+P332+P313+P362+P364 P303+P361+P353 P305+P351+P338 P305+P351+P338+P337+P313 P332+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P370+P378 P403+P235 P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word	Danger
Safety Statements
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S29 Do not empty into drains 不要排入下水道； S33 Take precautionary measures against static discharges 对静电采取预防措施； S36 Wear suitable protective clothing 穿戴适当的防护服； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护； S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
R11 Highly flammable 非常易燃 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number	1993 UN 1993 3/PG 2
Storage condition	2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing Group	II
Hazard Class	3

经由钯催化的碳环合成高取代的茚类；铑催化的和二溴苯硼酸的反应合成二氢茚酮(indenones)；在Cp2Zr(H)CI存在下把醛转化成1,3-二烯烃等等。

{TRC} Zlotos, D., et al.: J. Med. Chem., 47, 3561 (2004),

{TRC} Falck, J., et al.: Bioorg. Med. Chem. Lett., 14, 4987 (2004),

{SA} J. Am. Chem. Soc. 129 , 5766, (2007) 摘要

{SA} Beil. 4 ,IV,3938

{ALD} Beilstein: 4,IV,3938

{uni_hamburg} Short: III/35F

{ALF} Alkylation of the lithio-derivative proceeds with only a small amount of allylic rearrangement to the allene, and is thus a useful route to substituted terminal alkynes: Tetrahedron Lett., 5041 (1968):

6224-91-5 H38919 1-(Trimethylsilyl)propyne
1-(三甲基硅基)丙炔

化学属性

Mol. Formula	C6H12Si
Mol. Weight	112.24
Refractive index	1.4190 to 1.4210
Boiling Point	99-100°C at 760 mmHg
Density	0.758
Flash Point	4°C
TSCA	No
Melting Point	-69°C
Vapor Density	>;1 (vs air)

*以上化合物性质及应用等信息仅供参考

手性催化剂及配体

合成砌块

医药中间体

1-(Trimethylsilyl)propyne 1-(三甲基硅基)丙炔

规格: 98%

化学属性

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