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1-Hexyne 1-己炔

规格: 97%
CAS: 693-02-7
产品编号: H22257
MDL: MFCD00009504
品牌: INFI
Chemical Name1-Hexyne
CAS Number693-02-7
PubChem Substance ID12732
EC Number211-736-9
Beilstein Registry Number635687
MDL NumberMFCD00009504
Reaxys-RN635687
Synonym Butyl acetyne HEXYNE(1-) n-Butylacetylene 正丁基乙炔 1-hexine N-butylacetylene 1-已炔 丁基乙炔;正丁基乙炔 hex-1-yne Hexin-(1) N-BUTYLACETYLENE 丁基乙炔 5-Hexyne 1-hexyne Hexyne 1-Hexin 1-HEXYNE 1-己炔,98+% 1-Hexyne (8CI, 9CI) hexyne-1 1-己炔 Butylacetylene 1-Hexyne98% 1-Hexyne,>99% C4H9CequivCH Hex-1-yne
Chemical Name Translation1-Hexyne 1-己炔
LabNetwork Molecule IDLN00241730
InChIInChI=1S/C6H10/c1-3-5-6-4-2/h1H,4-6H2,2H3
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NATUAS Nature.  (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736)
   V.1-    1869-  Volume(issue)/page/year: 174,737,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JACSAT Journal of the American Chemical Society.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1879-  Volume(issue)/page/year: 79,2311,1957

WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H319 Causes serious eye irritation 严重刺激眼睛
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes 3
    RTECSMQ9691000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P310
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P331 Do NOT induce vomiting.. 不要催吐。
    • P332+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
    • P370+P378
    • P403+P235
    • P405 Store locked up. 上锁保管。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S36 Wear suitable protective clothing 穿戴适当的防护服;
      • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
          UN Number 3295
          Packing GroupII
          Hazard Class3
          Storage condition 0-6°C 储存温度2-8°C 储存温度2-8℃,充氩保存
          Warnings 危化品目录(2015)
        • 用于有机合成。
        • {uni_hamburg} Short: II/27B
        • {ALFA} The dilithiation of 1-alkynes with n-BuLi, followed by alkylation at the 3-position, is illustrated for 1-hexyne: Org. Synth. Coll., 6, 595 (1988). For [2 + 2] cycloaddition with dichloroketene to give a substituted cyclobutenone, see: Org. Synth. Coll., 8, 82 (1993).
        • {ALD} Beilstein:1,253
        • 693-02-7 H22257 1-Hexyne
1-己炔

          化学属性

          Mol. FormulaC6H10
          Mol. Weight82.15
          Refractive index1.3980 to 1.4010
          Boiling Point71-72
          Density0.715
          Melting Point-132
          Flash Point-21°C(lit.)
          TSCAYes
          Vapor Pressure253 mmHg ( 37.7 °C)
          Solubility不溶于水,溶于乙醇、乙醚、苯等。
          Stability对空气敏感