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1-Hexyne 1-己炔

规格: 97%

CAS: 693-02-7

产品编号: H22257

MDL: MFCD00009504

品牌: INFI

Chemical Name	1-Hexyne
CAS Number	693-02-7
PubChem Substance ID	12732
EC Number	211-736-9
Beilstein Registry Number	635687
MDL Number	MFCD00009504
Reaxys-RN	635687
Synonym	Butyl acetyne HEXYNE(1-) n-Butylacetylene 正丁基乙炔 1-hexine N-butylacetylene 1-已炔丁基乙炔;正丁基乙炔 hex-1-yne Hexin-(1) N-BUTYLACETYLENE 丁基乙炔 5-Hexyne 1-hexyne Hexyne 1-Hexin 1-HEXYNE 1-己炔,98+% 1-Hexyne (8CI, 9CI) hexyne-1 1-己炔 Butylacetylene 1-Hexyne98% 1-Hexyne,>99% C4H9CequivCH Hex-1-yne
Chemical Name Translation	1-己炔粗品
LabNetwork Molecule ID	LN00241730
InChI	InChI=1S/C6H10/c1-3-5-6-4-2/h1H,4-6H2,2H3

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NATUAS Nature.  (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736)
   V.1-    1869-  Volume(issue)/page/year: 174,737,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JACSAT Journal of the American Chemical Society.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1879-  Volume(issue)/page/year: 79,2311,1957

WGK Germany	3
Hazard statements
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命 H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	3
RTECS	MQ9691000
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P233 Keep container tightly closed. ?保持容器密闭。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。 P242 Use only non-sparking tools. 只能使用无火花工具。 P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P310 P302+P352 P303+P361+P353 P304+P340 P305+P351+P338 P305+P351+P338+P337+P313 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P331 Do NOT induce vomiting.. 不要催吐。 P332+P313 P337+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P370+P378 P403+P233 P403+P235 P405 Store locked up. 上锁保管。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word	Danger
Safety Statements
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36 Wear suitable protective clothing 穿戴适当的防护服； S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
Risk Statements
R11 Highly flammable 非常易燃 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
UN Number	3295
Packing Group	II
Hazard Class	3
Storage condition	0-6°C 储存温度2-8°C 储存温度2-8℃,充氩保存
Warnings	危化品目录(2015)
Restrict	危险品

用于有机合成。

{uni_hamburg} Short: II/27B

{ALFA} The dilithiation of 1-alkynes with n-BuLi, followed by alkylation at the 3-position, is illustrated for 1-hexyne: Org. Synth. Coll., 6, 595 (1988). For [2 + 2] cycloaddition with dichloroketene to give a substituted cyclobutenone, see: Org. Synth. Coll., 8, 82 (1993).

{ALD} Beilstein:1,253

化学属性

Mol. Formula	C6H10
Mol. Weight	82.14
Refractive index	1.3980 to 1.4010
Boiling Point	71 - 72 °C
Density	0.695
Melting Point	-132 °C
Flash Point	-20 °C
TSCA	Yes
Vapor Pressure	253 mmHg ( 37.7 °C)
Solubility	不溶于水，溶于乙醇、乙醚、苯等。
Stability	对空气敏感

*以上化合物性质及应用等信息仅供参考

手性催化剂及配体

合成砌块

医药中间体

1-Hexyne 1-己炔

规格: 97%

化学属性

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